Redox-active and electrochromic polymers from triarylamine end-capped, 2,7-bis(diphenylamino)naphthalene-cored dicarboxamides
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DOI: 10.1016/j.eurpolymj.2017.03.016
Abstract: Abstract Two N-phenylcarbazole and triphenylamine end-capped, 2,7-bis(diphenylamino)naphthalene-cored dicarboxamides were prepared by the condensation reactions from N,N′-bis(4-aminophenyl)-N,N′-bis(4-methoxyphenyl)-2,7-naphthalenediamine with two equivalent amount of N-(4-carboxyphenyl)carbazole and 4-carboxytriphenylamine, respectively. These two dicarboxamides can be electropolymerized into electroactive films on… read more here.
Keywords: naphthalene cored; bis; diphenylamino naphthalene; end capped ... See more keywords
Visible-Light-Triggered Monofluoromethylation of Alkenes by Strongly Reducing 1,4-Bis(diphenylamino)naphthalene Photoredox Catalysis
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DOI: 10.1021/acscatal.9b00473
Abstract: Monofluoromethyl (CH2F) radical can be easily generated from a sulfoximine-based precursor (CH2F–S(=O)(=NTs)-Ph) by the action of visible-light metal-free photoredox catalysis with readily accessible 1,4-bis(diphenylamino)naphthalene. The catalyst design based on the high excitation energy (E0,0) and… read more here.
Keywords: monofluoromethylation alkenes; bis diphenylamino; photoredox catalysis; visible light ... See more keywords