Complexation of U(VI) with diphenyldithiophosphinic acid: spectroscopy, structure and DFT calculations
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DOI: 10.1007/s10967-018-5844-y
Abstract: The complexation of U(VI) with diphenyldithiophosphinic acid (denoted as HL) in acetonitrile was studied by UV–Vis, FT-IR, crystallography and DFT calculations. UV–Vis absorption spectrophotometry implies that three successive complexes, UO2L+, UO2L2, UO2L3−, form in the… read more here.
Keywords: diphenyldithiophosphinic acid; dft calculations; complexation diphenyldithiophosphinic; spectroscopy ... See more keywords
Reactions of diphenyldithiophosphinic acid with N-alkyl-2-chloro-2-methylpropanimines
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DOI: 10.1007/s11172-018-2156-x
Abstract: In contrast to O,O-dialkyldithiophosphoric acids, the reactions of more weak diphenyldithiophosphinic acid with N-alkyl-2-chloro-2-methylpropanimines at a 1 : 1 reagent ratio follow two pathways. The first route is nucleophilic substitution of the chlorine atom of… read more here.
Keywords: chloro methylpropanimines; diphenyldithiophosphinic acid; alkyl chloro; acid alkyl ... See more keywords