Nanoscale Saturn Systems Based on C60/70 Bucky Ball and a Newly Designed [4]Cyclopara-1,2-diphenylethylene Hoop: A Strategy for Fullerene Encapsulation Release and Selective Recognition for C70.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.3c00665
Abstract: A new carbonaceous nanohoop, [4]cyclopara-1,2-diphenylethylene ([4]CPDPE, composed by four 1,2-diphenylethylene units linked via the para of the phenyls), is designed together with two rational synthesis paths being proposed. The Saturn-like host-guest systems formed with the… read more here.
Keywords: fullerene encapsulation; diphenylethylene; c60; cyclopara diphenylethylene ... See more keywords
Reversible addition and hydrogenation of 1,1-diphenylethylene with a barium complex.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt01874c
Abstract: Treatment of the barium hydride complex [(TpAd,iPr)Ba(μ-H)]2 (TpAd,iPr = hydrotris(3-adamantyl-5-isopropyl-pyrazolyl)borate) (1) with an excess amount of 1,1-diphenylethylene (DPE) afforded the corresponding mono-DPE adduct [(TpAd,iPr)Ba(η6-Ph)C(Ph)Me] (2) and di-DPE adduct [(TpAd,iPr)Ba(η6-Ph)C(Ph)-CH2-C(Ph)2Me] (3), which could convert to each… read more here.
Keywords: diphenylethylene; tpad ipr; barium; hydrogenation ... See more keywords