Synthesis and characterization of 1'-(diphenylphosphino)-1-isocyanoferrocene, an organometallic ligand combining two different soft donor moieties, and its Group 11 metal complexes.
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DOI: 10.1039/c7dt02336g
Abstract: The development of a practical synthesis of 1'-(diphenylphosphino)-1-aminoferrocene (2) and its P-borane adduct (2B) allowed the facile preparation of 1'-(diphenylphosphino)-1-isocyanoferrocene (1). This compound combining two specific soft-donor moieties was studied as a ligand for univalent… read more here.
Keywords: soft donor; group metal; combining two; diphenylphosphino ... See more keywords
Transforming PPh3 into bidentate phosphine ligands at Ru-Zn heterobimetallic complexes.
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DOI: 10.1039/c9dt03106e
Abstract: The reaction of [Ru(PPh3)3Cl2] with excess ZnMe2 led to P-C/C-H bond activation and P-C/C-C bond formation to generate a chelating diphenylphosphinobenzene ligand as well as a cyclometallated (diphenylphosphino)biphenyl group in the final product of the… read more here.
Keywords: pph3; bond; dppbz; biphenyl ... See more keywords
Efficient catalytic transfer hydrogenation reactions of carbonyl compounds by Ni(II)-diphosphine complexes
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DOI: 10.1080/00958972.2020.1837784
Abstract: Abstract The catalytic transfer hydrogenation reactions of a series of aromatic and aliphatic carbonyl compounds were investigated using divalent Ni(II)-diphosphine complexes, [L2NiCl2] (where L2 = 1,1-bis(diphenylphosphino)methane (dppm), 1,2-bis(diphenylphosphino)ethane (dppe), 1,3-bis(diphenylphosphino)propane (dppp), 1,1-bis(diphenylphosphino)ferrocene (dppf), and N-butyl-N-(diphenylphosphino)-1,1-diphenylphosphinamine… read more here.
Keywords: catalytic transfer; diphenylphosphino; hydrogenation reactions; transfer hydrogenation ... See more keywords