Radical-initiated P,P-metathesis reactions of diphosphanes: evidence from experimental and computational studies.
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DOI: 10.1039/d1dt01013a
Abstract: By combining the diphosphanes Ar2P-PAr2, where Ar = C6H5, 4-C6H4Me, 4-C6H4OMe, 3,5-C6H3(CF3)2, it has been shown that P,P-metathesis generally occurs rapidly under ambient conditions. DFT calculations have shown that the stability of unsymmetrical diphosphanes Z2P-PZ'2… read more here.
Keywords: radical initiated; initiated metathesis; metathesis reactions; reactions diphosphanes ... See more keywords