Hydrogenation of CO2 in Water Using a Bis(diphosphine) Ni–H Complex
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DOI: 10.1021/acscatal.7b00350
Abstract: The water-soluble Ni bis(diphosphine) complex [NiL2](BF4)2 (L = 1,2-[bis(dimethoxypropyl)phosphino]ethane and the corresponding hydride, [HNiL2]BF4, were synthesized and characterized. These complexes were specifically designed for CO2 hydrogenation. For HNiL2+, the hydricity (ΔG°H–) was determined to be… read more here.
Keywords: hydrogenation co2; diphosphine complex; water; hydrogenation ... See more keywords