Two-Coordinate, Late First-Row Transition Metal Amido Derivatives of the Bulky Ligand -N(SiPr i3)Dipp (Dipp = 2,6-diisopropylphenyl): Effects of the Ligand on the Stability of Two-Coordinate Copper(II) Complexes.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b01159
Abstract: The synthesis and spectroscopic, structural, and magnetic characterization of the quasi-linear metal(II) bis(amides) M{N(SiPr i3)Dipp}2 [Dipp = C6H3-2,6-Pr i3; M = Fe (1), Co (2), or Zn (3)] are described. The magnetic data demonstrate the… read more here.
Keywords: two coordinate; copper; metal; dipp ... See more keywords
Ancillary Steric Effects on the Activation of SiH Bonds in Arylsilazido Rare-Earth Compounds
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DOI: 10.1021/acs.organomet.1c00162
Abstract: Three new hydridosilazido ligands, −N(SiHMe2)Aryl (Aryl = Ph, 2,6-C6Me2H3 (dmp), 2,6-C6iPr2H3 (dipp)) and their rare-earth complexes Ln{N(SiHMe2)Aryl}3(THF)n (Ln = Sc, Y, Lu; Aryl = Ph, n = 2; Aryl = dmp, n = 1; Aryl… read more here.
Keywords: thf; sihme2; aryl; rare earth ... See more keywords
Widely contrasting outcomes from the use of tris(pentafluorophenyl)bismuth or pentafluorophenylsilver as oxidants in the reactions of lanthanoid metals with N,N'-diarylformamidines.
Sign Up to like & getrecommendations! Published in 2020 at "Dalton transactions"
DOI: 10.1039/d0dt03044a
Abstract: Reactions of lanthanoid metals with tris(pentafluorophenyl)bismuth or pentafluorophenylsilver and two widely disparate formamidines, N,N'-bis(2,6-difluorophenyl)formamidine (DFFormH) and N,N'-bis(2,6-diisopropylphenyl)formamidine (DippFormH) have been investigated as possible redox transmetallation/protolysis (RTP) syntheses of lanthanoid formamidinates. Thus, [Ln(DFForm)3(thf)] (Ln = Lu,… read more here.
Keywords: c6f5 5diox; lanthanoid metals; dfform; thf ... See more keywords
Alkali metal influences in aluminyl complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt02111k
Abstract: The previously reported potassium aluminyl complex [(BDI-H)Al-K+]2 was converted in Li+ or Na+ salts by a salt metathesis reaction with Li(BPh4) or Na(BPh4), respectively; BDI-H = dianionic [(DIPP)N-C(Me)C(H)-C(CH2)-N(DIPP)2-] and DIPP = 2,6-diisopropylphenyl. The Rb and… read more here.
Keywords: dipp; aluminyl; aluminyl complexes; bdi ... See more keywords
Stabilization of a high-spin three-coordinate Fe(iii) imidyl complex by radical delocalization
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DOI: 10.1039/d2sc02699f
Abstract: High-spin, late transition metal imido complexes have attracted significant interest due to their group transfer reactivity and catalytic C–H activation of organic substrates. Reaction of a new two-coordinate iron complex, Fe{N(tBu)Dipp}2 (1, Dipp = 2,6-diisopropylphenyl),… read more here.
Keywords: 320 320; dipp; imidyl; tbu dipp ... See more keywords
An acyclic aluminyl anion.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d3cc01317k
Abstract: The potassium aluminyl complex K2[Al{N(Dipp)SiMe3}2]2 was synthesised via reduction of [AlI{N(Dipp)SiMe3}2] (Dipp = 2,6-i-Pr2C6H3). This represents the first example of an aluminyl anion supported by an acyclic ligand framework. Attempts to yield the same structure… read more here.
Keywords: acyclic aluminyl; dipp sime3; dipp; aluminyl anion ... See more keywords