Direct C–H Allylation of Unactivated Alkanes by Cooperative W/Cu Photocatalysis
Sign Up to like & getrecommendations! Published in 2022 at "Organic Letters"
DOI: 10.1021/acs.orglett.2c02887
Abstract: Here we report a photocatalytic methodology that enables the direct allylation of strong aliphatic C–H bonds with simple allylic chlorides. The method relies on a cooperative interaction of two metal catalysts in which the decatungstate… read more here.
Keywords: unactivated alkanes; allylation; direct allylation; cooperative photocatalysis ... See more keywords
Homogeneous Sc(OTf)3-Catalyzed Direct Allylation Reactions of General Alcohols with Allylsilanes
Sign Up to like & getrecommendations! Published in 2018 at "ACS Omega"
DOI: 10.1021/acsomega.8b01627
Abstract: Homogeneous Sc(OTf)3 used in nitromethane showed excellent catalytic activity for the direct allylation reactions of general alcohols including benzylic, propargylic, allylic, and some aliphatic alcohols with allyltrimethylsilane under mild and neutral reaction conditions. Metal-free β-silyl-substituted… read more here.
Keywords: direct allylation; allylation reactions; reactions general; general alcohols ... See more keywords