An overview on the progress and development on the palladium catalyzed direct cyanation
Sign Up to like & getrecommendations! Published in 2021 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2020.119956
Abstract: Abstract Generation of the positive CN ion and the corresponding direct cyanation are both extremely important for cyanation of aromatic compounds. Hereby, we would like to report the simultaneous use of the new Pd nano-catalyst… read more here.
Keywords: development palladium; direct cyanation; palladium catalyzed; cyanation ... See more keywords
Silver-Mediated Direct C-H Cyanation of Terminal Alkynes with N-Isocyanoiminotriphenylphosphorane.
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DOI: 10.1021/acs.orglett.7b02743
Abstract: A direct cyanation of terminal alkynes for the synthesis of propionitrile derivatives, with the aid of silver salt using water additive, has been achieved. The cyano source used is N-isocyanoiminotriphenylphosphorane, which is nontoxic, safe, and… read more here.
Keywords: cyanation terminal; silver mediated; terminal alkynes; direct cyanation ... See more keywords
Boron Lewis Acid Catalysis Enables the Direct Cyanation of Benzyl Alcohols by Means of Isonitrile as Cyanide Source
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DOI: 10.3390/molecules28052174
Abstract: The development of an efficient and straightforward method for cyanation of alcohols is of great value. However, the cyanation of alcohols always requires toxic cyanide sources. Herein, an unprecedented synthetic application of an isonitrile as… read more here.
Keywords: cyanide source; cyanation; cyanide; direct cyanation ... See more keywords