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Published in 2020 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c11494
Abstract: Non-natural photoenzymatic reactions reported to date have depended on the excitation of electron donor-acceptor complexes formed between substrates and cofactors within protein active sites to facilitate electron transfer. While this mechanism has unlocked new reactivity,…
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Keywords:
direct excitation;
excitation flavin;
reductions enabled;
excitation ... See more keywords
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Published in 2025 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.5c17266
Abstract: We report a catalytic strategy for generating carbon-centered radicals from organoboron compounds under deep-red to near-infrared (DR to NIR) light irradiation via direct excitation of substrate-catalyst complexes. Aza-dipyrromethene (ADP) catalysts form photoactive borate intermediates that…
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Keywords:
direct excitation;
red near;
deep red;
excitation ... See more keywords
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Published in 2024 at "Nature Physics"
DOI: 10.1038/s41567-024-02720-9
Abstract: Helices and spirals, prevalent across various physical systems, play a crucial role in characterizing symmetry, describing dynamics and enabling unique functionalities, all stemming from their inherent simplicity and chiral nature. Helical excitations on quantized vortices,…
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Keywords:
direct excitation;
excitation kelvin;
waves quantized;
quantized vortices ... See more keywords
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Published in 2022 at "Methods and Applications in Fluorescence"
DOI: 10.1088/2050-6120/ac4c9a
Abstract: We studied room temperature phosphorescence of tryptophan (TRP) embedded in poly (vinyl alcohol) films. With UV (285 nm) excitation, the phosphorescence spectrum of tryptophan appears at about 460 nm. We also observed the TRP phosphorescence…
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Keywords:
excitation tryptophan;
excitation;
phosphorescence;
direct excitation ... See more keywords