Efficient direct fluorination of the B12H11(NH3)− anion in acetonitrile and comparison of the structures of Na(H2O)4(B12F11(NH3)), Na(H3O)(H2O)3(B12F12), and Na2(H2O)4(B12F12)
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Fluorine Chemistry"
DOI: 10.1016/j.jfluchem.2017.06.006
Abstract: Abstract An efficient procedure for the direct per- B -fluorination of the potassium salt of the mono-ammonioborane anion B 12 H 11 (NH 3 ) − in anhydrous CH 3 CN with 20:80 F 2 :N… read more here.
Keywords: anion; direct fluorination; h2o b12f12; fluorination ... See more keywords
Industrial Preparation of Self-Lubricating Polyurethane via Direct Fluorination with Gaseous Fluorine
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DOI: 10.1021/acsomega.2c03019
Abstract: Fluorination modification is an effective way to improve the friction property of a polymer; however, current preparation of fluorine-containing polymers is limited by the high cost and complex synthesis. Here, an industrial fluorination strategy with… read more here.
Keywords: gaseous fluorine; fluorination; friction; fluorine ... See more keywords
Amide-assisted radical strategy: metal-free direct fluorination of arenes in aqueous media
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DOI: 10.1039/c7gc00356k
Abstract: A metal- and initiator-free direct fluorination of arenes with the assistance of an amide group is developed. This reaction proceeded under simple aqueous conditions with good functional group tolerance and ortho–para selectivity, and is highly… read more here.
Keywords: free direct; direct fluorination; metal; fluorination arenes ... See more keywords
Effect of Direct Fluorination on the Transport Properties and Swelling of Polymeric Materials: A Review
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DOI: 10.3390/membranes11090713
Abstract: Fluorine-containing polymers occupy a peculiar niche among conventional polymers due to the unique combination of physicochemical properties. Direct surface fluorination of the polymeric materials is one of the approaches for the introduction of fluorine into… read more here.
Keywords: fluorination transport; effect direct; direct fluorination; fluorination ... See more keywords