Rhodium-catalysed direct formylmethylation using vinylene carbonate and sequential dehydrogenative esterification.
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DOI: 10.1039/d1cc03362j
Abstract: A rhodium-catalysed direct formylmethylation adopting vinylene carbonate as an ethynol equivalent is reported. The developed catalytic system is further utilised for the oxidant-free production of esters with the liberation of hydrogen gas. Some control experiments… read more here.
Keywords: direct formylmethylation; rhodium catalysed; vinylene carbonate; catalysed direct ... See more keywords