Direct B-H Functionalization of Icosahedral Carboranes via Hydrogen Atom Transfer.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c01314
Abstract: The efficient and selective functionalization of icosahedral carboranes (C2B10H12) at the boron vertexes is a long-standing challenge owing to the presence of 10 inert B-H bonds in a similar chemical environment. Herein, we report a… read more here.
Keywords: hydrogen atom; functionalization; carboranes via; functionalization icosahedral ... See more keywords
Direct functionalization of cyclic ethers with maleimide iodides via free radial-mediated sp3 C-H activation.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical communications"
DOI: 10.1039/d1cc01484f
Abstract: Cyclic ethers are important scaffolds employed in the synthesis of various natural products and pharmaceutical ingredients. A novel free radical-initiated reaction between cyclic ethers and maleimide iodides through C-H activation is developed, avoiding the use… read more here.
Keywords: activation; maleimide iodides; cyclic ethers; ethers maleimide ... See more keywords