Visible-light-induced Mn(0)-catalyzed direct C-3 mono-, di- and perfluoroalkylation reactions of 2H-indazoles.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc05021h
Abstract: A general and efficient method for visible-light-driven fluoroalkylation, such as difluoromethylphosphonation, difluoroacetamidation, monofluoromethylation, difluoromethylation, and perfluoroalkyalation, of 2H-indazoles using an inexpensive Mn2(CO)10 photocatalyst has been developed. The present methodology affords a new series of C-3… read more here.
Keywords: direct mono; light induced; catalyzed direct; induced catalyzed ... See more keywords
Recent trends in direct mono-, di-, and tri-fluoromethyl(thiol)ation of S-H bonds
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Sulfur Chemistry"
DOI: 10.1080/17415993.2019.1598410
Abstract: ABSTRACT Fluorine-containing organosulfur molecules are an important class of biologically active compounds and potential drug candidates. Consequently, significant effort has been made to exploit efficient strategies towards the synthesis of the titled compounds. Recently, direct… read more here.
Keywords: mono tri; direct mono; tri fluoromethyl; ation bonds ... See more keywords