Directed, Remote Dirhodium C(sp3)-H Functionalization, Desaturative Annulation, and Desaturation.
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DOI: 10.1021/jacs.2c07427
Abstract: Iminodirhodium reactive intermediates generated in situ from O-tosyloximes using Rh2(esp)2 in CH2Cl2 at rt were exploited for an agile trichotomy of challenging transformations: (1) remote C-H functionalizations using an exceptionally broad diversity of inorganic and… read more here.
Keywords: desaturative annulation; annulation; remote dirhodium; directed remote ... See more keywords