Iridium(I) complexes with bidentate NHC ligands as catalysts for dehydrogenative directed C-H silylation.
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DOI: 10.1039/d2cc06865f
Abstract: A series of (NHC)(cod)Ir(I) complexes bearing NHC-carboxylate ligands were efficiently synthesized and fully characterized. Their solid-state structures confirmed the bidentate coordination mode of these LX-type NHC ligands. These unprecedented iridium(I) complexes demonstrated efficient catalytic activities… read more here.
Keywords: directed silylation; iridium complexes; nhc ligands; dehydrogenative directed ... See more keywords