Synthesis of rhenacyclopentadienes and η2:η2-diyne complexes from a labile dirhenium carbonyl and π-conjugated 1,7-octadiynes: Structural and photophysical characterization
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2018.12.003
Abstract: Abstract A series of dirhenium carbonyl compounds containing π-conjugated diyne ligands and symmetrical 2,5-bis(aryl)rhenacyclopentadienes has been synthesized by reaction of [Re2(CO)8(CH3CN)2] and 1,8-bis(aryl)-1,7-octadiyne derivatives [aryl = 2-thienyl (a), 2-pyridyl (b), 2-quinolyl (c) and 9-phenanthrenyl (d)]. We found… read more here.
Keywords: diyne complexes; re2 ch3cn; dirhenium carbonyl; bis aryl ... See more keywords
Reductive coupling of diisopropylcarbodiimide by a dirhenium carbonyl complex
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2019.06.027
Abstract: Abstract The reaction of Re 2 (CO) 8 (μ-H)[μ-η 2 -C(H) = C(H)Bu n ] with N , N ′-diisopropylcarbodiimide yielded the new rhenium diamidinate complex [Re(CO) 4 ] 2 [(μ-C 2 (N{iPr}) 4 ], 2 ,… read more here.
Keywords: diisopropylcarbodiimide dirhenium; coupling diisopropylcarbodiimide; dirhenium carbonyl; ligand ... See more keywords
Synthesis and Chemistry of Ammonioethenyl and Phosphonioethenyl Ligands in Zwitterionic Dirhenium Carbonyl Complexes.
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DOI: 10.1021/acs.inorgchem.2c01471
Abstract: New zwitterionic dirhenium carbonyl complexes containing ammonioethenyl and phosphonioethenyl ligands have been synthesized and studied. The reaction of Re2(CO)10 with C2H2 and Me3NO yielded the dirhenium complex Re2(CO)9(NMe3) (6) and the new zwitterionic complex Re2(CO)9[η1-E-2-CH═CH(NMe3)]… read more here.
Keywords: dirhenium carbonyl; re2; carbonyl complexes; chemistry ... See more keywords
Replacement of the phosphodiester backbone between canonical nucleosides with a dirhenium carbonyl "click" linker-a new class of luminescent organometallic dinucleoside phosphate mimics.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d2dt03995h
Abstract: The first-in-class luminescent dinucleoside phosphate analogs with a [Re2(μ-Cl)2(CO)6(μ-pyridazine)] "click" linker as a replacement for the natural phosphate group are reported together with the synthesis of luminescent adenosine and thymidine derivatives having the [Re2(μ-Cl)2(CO)6(μ-pyridazine)] entity… read more here.
Keywords: phosphate; luminescent; dirhenium carbonyl; class luminescent ... See more keywords