Effect of Equatorial Ligand Substitution on the Reactivity with Proteins of Paddlewheel Diruthenium Complexes: Structural Studies
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DOI: 10.1021/acs.inorgchem.2c04103
Abstract: The paddlewheel [Ru2Cl(O2CCH3)4] complex was previously reported to react with the model protein hen egg white lysozyme (HEWL), forming adducts with two diruthenium moieties bound to Asp101 and Asp119 side chains upon the release of… read more here.
Keywords: reactivity proteins; paddlewheel diruthenium; effect equatorial; diruthenium ... See more keywords
Anthraquinone-bridged diruthenium(II) complexes inhibit migration and invasion of human hepatocarcinoma MHCC97-H cells
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DOI: 10.1039/c7qi00149e
Abstract: Metastasis is a major health threat for most cancer patients, thus anti-metastasis treatments that reduce cell migration and invasion are critical for cancer treatment. In this study, four anthraquinone-bridged diruthenium(II) complexes, [(bpy)2Ru(L)Ru(bpy)2]4+ (Ru1, L =… read more here.
Keywords: anthraquinone bridged; invasion; bis imidazo; diruthenium complexes ... See more keywords
Hammett-law Correlation in the Electron-donation Ability of trans-Heteroleptic Benzoate-bridged Paddlewheel-type Diruthenium(II,II) Complexes
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DOI: 10.1246/cl.180155
Abstract: A series of trans-heteroleptic paddlewheel-type diruthenium(II,II) complexes [Ru2(2,6-(CF3)2PhCO2)2(p-RPhCO2)2(THF)2] was synthesized by substituting para-R-substituted benzoate ligands (p-RPhCO2−, R = CF3, Cl, F, H, Ph, Me, MeO, OH) in [Ru2(p-RPhCO2)4(THF)2] with 2,6-bis(trifluoromethyl)benzoate (2,6-(CF3)2PhCO2−). The redox potential (E1/2)… read more here.
Keywords: diruthenium complexes; trans heteroleptic; paddlewheel type; type diruthenium ... See more keywords