A zwitterionic disilanylium from an unsymmetrical disilene.
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DOI: 10.1039/d2cc06954g
Abstract: The reaction of PhC(NtBu)2SiSi(SiMe3)3 (1) with Me3SiCH2Cl afforded an unsymmetrical sp2-sp3 disilene, 2, with concomitant elimination of Me3SiCl. The analogous reaction with PhC(NtBu)2SiCl resulted in the oxidative addition of the C-Cl bond at the Si(II)… read more here.
Keywords: unsymmetrical disilene; disilene; zwitterionic disilanylium; disilanylium unsymmetrical ... See more keywords