Linking two worlds in polymer chemistry: The influence of block uniformity and dispersity in amphiphilic block copolypeptoids on their self-assembly.
Sign Up to like & getrecommendations! Published in 2019 at "Biopolymers"
DOI: 10.1002/bip.23259
Abstract: The self-assembly of block copolymers has captured the interest of scientists for many decades because it can induce ordered structures and help to imitate complex structures found in nature. In contrast to proteins, nature's most… read more here.
Keywords: self assembly; block; dispersity; chemistry ... See more keywords
The influence of the cation type of ionic liquid on the production of nanocrystalline cellulose and mechanical properties of chitosan-based biocomposites
Sign Up to like & getrecommendations! Published in 2019 at "Cellulose"
DOI: 10.1007/s10570-019-02412-1
Abstract: In this paper three newly synthesized imidazolium ionic liquids with different structures of cations were used for hydrolysis of cellulose. It was found that type of the cation has a great influence on particle size… read more here.
Keywords: ionic liquid; cation; liquid; dispersity ... See more keywords
Stabilization of complex morphologies in highly disperse AB diblock copolymers
Sign Up to like & getrecommendations! Published in 2020 at "Polymer"
DOI: 10.1016/j.polymer.2020.122519
Abstract: Abstract Block copolymers have the unique property to self-assemble into ordered microstructures with well-defined periodicity. Among the various attainable microdomain morphologies, complex morphologies with inherent structural connectivity are highly desirable. While such structures are difficult… read more here.
Keywords: complex morphologies; block; dispersity; diblock copolymers ... See more keywords
“Living” Polymer Dispersity Quantification for Nitroxide-Mediated Polymerization Systems by Mimicking a Monodispersed Polymer Blending Strategy
Sign Up to like & getrecommendations! Published in 2020 at "Macromolecules"
DOI: 10.1021/acs.macromol.0c02029
Abstract: The quantification of dispersity is an indispensable part of characterizing polymers. In this work, general dispersity equations for “living” polymers obtained by nitroxide-mediated polymerization ... read more here.
Keywords: dispersity; polymer; mediated polymerization; nitroxide mediated ... See more keywords
Electrochemically-Initiated RAFT Synthesis of Low Dispersity Multiblock Copolymers by Seeded Emulsion Polymerization
Sign Up to like & getrecommendations! Published in 2023 at "ACS Macro Letters"
DOI: 10.1021/acsmacrolett.3c00021
Abstract: We describe electrochemically initiated emulsion polymerization with reversible addition-fragmentation chain transfer (eRAFT) to form well-defined multiblock copolymers with low molar mass dispersity. We demonstrate the utility of our emulsion eRAFT process with the synthesis of… read more here.
Keywords: dispersity; multiblock copolymers; emulsion polymerization; emulsion ... See more keywords
Consequences of Dispersity on the Self-Assembly of ABA-Type Amphiphilic Block Co-Oligomers
Sign Up to like & getrecommendations! Published in 2018 at "ACS Macro Letters"
DOI: 10.1021/acsmacrolett.8b00168
Abstract: Intriguingly, little is known about the impact of dispersity on the crystallization driven self-assembly (CDSA) of amphiphilic block copolymers in aqueous media. Here, we investigate the influence of dispersity on the CDSA of ABA-type amphiphilic… read more here.
Keywords: self assembly; block; dispersity; amphiphilic block ... See more keywords
Effects of crystallinity and dispersity on the self-assembly behavior of block co-oligomers in water
Sign Up to like & getrecommendations! Published in 2020 at "Polymer Chemistry"
DOI: 10.1039/d0py01161d
Abstract: Self-assembly of block copolymers in solution is a topic of great interest in polymer science due to the potential for applications as a drug carrier system. In bulk, fully discrete polymers have been shown to… read more here.
Keywords: assembly behavior; block; self assembly; dispersity ... See more keywords
Signatures of continuous hexatic-liquid transition in two-dimensional melting.
Sign Up to like & getrecommendations! Published in 2021 at "Soft matter"
DOI: 10.1039/d0sm02199g
Abstract: Recent studies have shown that the melting of two-dimensional crystals can be either continuous or discontinuous, relying on multiple parameters such as particle stiffness, density, and particle size dispersity. However, what determines the continuity or… read more here.
Keywords: dispersity; transition; hexatic liquid; two dimensional ... See more keywords
Controlling Dispersity in Aqueous Atom Transfer Radical Polymerization: Rapid and Quantitative Synthesis of One-Pot Block Copolymers
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DOI: 10.1039/d1sc04241f
Abstract: The dispersity (Ɖ) of a polymer is a key parameter in material design, and variations in Ɖ can have a strong influence on fundamental polymer properties. Despite its importance, current... read more here.
Keywords: atom transfer; dispersity; transfer radical; dispersity aqueous ... See more keywords
Influence of the dispersity and molar mass distribution of conjugated polymers on the aggregation type and subsequent chiral expression.
Sign Up to like & getrecommendations! Published in 2023 at "Soft matter"
DOI: 10.1039/d3sm00163f
Abstract: This study aims to determine the influence of the dispersity on the aggregation of conjugated polymers and their subsequent chiral expression. Dispersity has been thoroughly investigated for industrial polymerizations, but research on conjugated polymers is… read more here.
Keywords: aggregation; influence; conjugated polymers; type ... See more keywords
Effectively Elevating Ceramic Fillers’ Dispersity in Gel Hybrid Electrolyte through Bridge–Linked Construction for High–Performance Lithium Metal Batteries
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DOI: 10.3390/batteries9050270
Abstract: Gel polymer-ceramic hybrid electrolytes (GHEs) have emerged as desirable candidates for preparing high energy density and excellent practicability gel batteries. However, the agglomeration of ceramic particles in polymer matrix leads to a decrease in cycling… read more here.
Keywords: bridge linked; ghe; lithium; llto ... See more keywords