OCS isomerization and dissociation kinetics from statistical models
Sign Up to like & getrecommendations! Published in 2018 at "Theoretical Chemistry Accounts"
DOI: 10.1007/s00214-018-2253-9
Abstract: AbstractIn this work computational modeling of the isomerization reactions of the linear OCS, CSO, COS, and the cyclic Δ-OCS structures, on the ground state Potential Energy Surface (PES), is performed using Rice–Ramsperger–Kassel–Marcus (RRKM), Semiclassical Transition… read more here.
Keywords: isomerization dissociation; ocs isomerization; dissociation; dissociation kinetics ... See more keywords
Methane Hydrate Intrinsic Dissociation Kinetics Measured in a Microfluidic System by Means of in Situ Raman Spectroscopy
Sign Up to like & getrecommendations! Published in 2018 at "Energy & Fuels"
DOI: 10.1021/acs.energyfuels.8b02833
Abstract: The present work investigates the dissociation kinetics of methane (sI) hydrate in a thermoelectrically cooled microfluidic system with in situ Raman spectroscopy. The dissociation profile of methane (sI) hydrate was measured under different Reynolds numbers… read more here.
Keywords: methane hydrate; dissociation kinetics; spectroscopy;
Unexpected Trends in the Stability and Dissociation Kinetics of Lanthanide(III) Complexes with Cyclen-Based Ligands across the Lanthanide Series.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c00520
Abstract: We report a detailed study of the thermodynamic stability and dissociation kinetics of lanthanide complexes with two ligands containing a cyclen unit, a methyl group, a picolinate arm, and two acetate pendant arms linked to… read more here.
Keywords: across lanthanide; kinetics lanthanide; dissociation; stability dissociation ... See more keywords
Ultra-stable biomembrane force probe for accurately determining slow dissociation kinetics of PD-1 blockade antibodies on single living cells.
Sign Up to like & getrecommendations! Published in 2020 at "Nano letters"
DOI: 10.1021/acs.nanolett.0c01360
Abstract: Immune checkpoint blockade with monoclonal antibodies (mAbs) that target programmed cell death protein-1 (PD-1) has remarkably revolutionized cancer therapy. Their binding kinetics measured by surface plasmon resonance do not always correlate well with their immunotherapeutic… read more here.
Keywords: force probe; ultra stable; dissociation kinetics; biomembrane force ... See more keywords
Efficient hydrogen production on MoNi4 electrocatalysts with fast water dissociation kinetics
Sign Up to like & getrecommendations! Published in 2017 at "Nature Communications"
DOI: 10.1038/ncomms15437
Abstract: Various platinum-free electrocatalysts have been explored for hydrogen evolution reaction in acidic solutions. However, in economical water-alkali electrolysers, sluggish water dissociation kinetics (Volmer step) on platinum-free electrocatalysts results in poor hydrogen-production activities. Here we report… read more here.
Keywords: water; dissociation kinetics; moni4 electrocatalyst; water dissociation ... See more keywords
Manipulating the water dissociation kinetics of Ni3N nanosheets via in situ interfacial engineering
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Materials Chemistry A"
DOI: 10.1039/c9ta03249e
Abstract: The sluggish water dissociation kinetics of Ni3N is significantly accelerated by in situ interfacial engineering. Owing to the unique synergy between Ni3N and MoO2, Ni3N/MoO2 displays exceptional alkaline HER activity. read more here.
Keywords: water dissociation; situ interfacial; kinetics ni3n; dissociation kinetics ... See more keywords