A dicationic distibine stabilized by intramolecular π-π interaction and second-sphere coordination.
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DOI: 10.1039/d5cc01730k
Abstract: A new type of pincer ligand (1) featuring an Sb(I) center and two pendent amine arms has been developed. The single electron oxidation of 1 produces a dicationic distibine (2). Crystallographic and computational investigations indicate… read more here.
Keywords: dicationic distibine; sphere coordination; distibine stabilized; second sphere ... See more keywords