Distinct Reactivity Modes of a Copper Hydride Enabled by an Intramolecular Lewis Acid.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c02937
Abstract: We disclose a 1,4,7-triazacyclononane (TACN) ligand featuring an appended boron Lewis acid. Metalation with Cu(I) affords a series of tetrahedral complexes including a boron-capped cuprous hydride. We demonstrate distinct reactivity modes as a function of… read more here.
Keywords: lewis acid; reactivity modes; hydride; distinct reactivity ... See more keywords
Shining light on the nitro group: distinct reactivity and selectivity.
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DOI: 10.1039/d4cc02582b
Abstract: The nitro moiety is an indispensable functional group in organic synthesis due to its facile introduction and reduction to the corresponding amines for a plethora of organic transformations. Owing to its distinct electronegative and conventional… read more here.
Keywords: group distinct; light nitro; nitro group; group ... See more keywords
Distinct reactivity of iron dihydride vs. iron(hydride)(borohydride) bearing the same bulky PNP ligand in hydrogenation of alkenes and alkynes.
Sign Up to like & getrecommendations! Published in 2025 at "Dalton transactions"
DOI: 10.1039/d5dt01350j
Abstract: An iron dihydrido complex [(Me4PNPiPr)Fe(H)2(N2)] with a bulky tetramethylated PNP pincer ligand, Me4PNPiPr, is an active catalyst for full hydrogenation of internal alkynes and alkenes, while its reactivity with terminal alkynes leads to its deactivation… read more here.
Keywords: hydrogenation; pnp; iron; ligand ... See more keywords