Chemical Versatility of [FeFe]-Hydrogenase Models: Distinctive Activity of [μ-C6H4-1,2-(κ2-S)2][Fe2(CO)6] for Electrocatalytic CO2 Reduction
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DOI: 10.1021/acscatal.8b03921
Abstract: The [FeFe]-hydrogenase model, [(μ-bdt)Fe2(CO)6] (1, bdt = benzene-1,2-dithiolato), displays distinctive activity from its analogous complex, [(μ-edt)Fe2(CO)6] (2, edt = ethane-1,2-dithiolato), for electrochemical CO2 reduction in acetonitrile with methanol or water as proton source. The maximum… read more here.
Keywords: fefe hydrogenase; co2 reduction; distinctive activity; fe2 ... See more keywords