Large Magnetic Anisotropy in Linear CoII Complexes – Ab Initio Investigation of the Roles of Ligand Field, Structural Distortion, and Conformational Dynamics
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DOI: 10.1002/ejic.201601192
Abstract: Linear or near linear bicoordinated mononuclear Co(II) complexes are studied as potential single molecule magnets due to the strong spin-orbit constant of Co(II) and its low coordination number that retains the metal orbital angular momentum… read more here.
Keywords: distortion conformational; structural distortion; ligand field; magnetic anisotropy ... See more keywords