Synthesis of 1,1-Disubstituted Indenes and Dihydronaphthalenes through C-C/C-C Bond-Forming Pd-Catalyzed Autotandem Reactions.
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DOI: 10.1021/acs.orglett.7b01870
Abstract: A novel synthesis of 1,1-disubstituted 1H-indenes is described involving the Pd-catalyzed cascade reaction between o-bromophenyl-β-bromostyrenes and N-tosylhydrazones in a process comprising the consecutive formation of two Csp3-C bonds on the same carbon atom: the cross-coupling… read more here.
Keywords: indenes dihydronaphthalenes; dihydronaphthalenes bond; synthesis disubstituted; bond forming ... See more keywords