Cleaner and stronger: how 8-quinolinolate facilitates formation of Co(III)-thiolate from Co(II)-disulfide complexes.
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DOI: 10.1039/d2dt02106d
Abstract: The formation of Co(III)-thiolate complexes from Co(II)-disulfide complexes using the anionic ligand 8-quinolinolate (quin-) has been studied experimentally and quantum chemically. Two Co(II)-disulfide complexes [Co2(LxSSLx)(Cl)4] (x = 1 or 2; L1SSL1 = 2,2'-disulfanediylbis(N,N-bis(pyridin-2-ylmethyl)ethan-1-amine; L2SSL2 =… read more here.
Keywords: disulfide complexes; thiolate; quin; iii thiolate ... See more keywords