Entropy-Driven Ring-Opening Disulfide Metathesis Polymerization for the Synthesis of Functional Poly(disulfide)s.
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DOI: 10.1002/marc.201700735
Abstract: Metal-free entropy-driven disulfide metathesis polymerization of unsaturated l-cystine based macrocycles produces high-molar-mass heterofunctional poly(disulfide)s, i.e., poly(ester-disulfide-alkene) and poly(amide-disulfide-alkene); Mwapp = 44-60 kDa, Ð > 1.7. The polymerization is fast and reaches equilibrium within 1-5 minutes… read more here.
Keywords: metathesis polymerization; polymerization; entropy driven; poly ... See more keywords