Determination of pH-independent rate constants of thiolate-disulfide redox transitions
Sign Up to like & getrecommendations! Published in 2018 at "New Journal of Chemistry"
DOI: 10.1039/c8nj01015c
Abstract: Microscopic rate constants were introduced and determined to quantify thiolate–disulfide kinetics of biological significance. The highly composite, codependent acid–base and redox processes of thiols could so far be characterized only in terms of apparent equilibrium… read more here.
Keywords: thiolate disulfide; disulfide redox; rate constants; rate ... See more keywords
Carbon disulfide: A redox mediator for organodisulfides in redox flow batteries
Sign Up to like & getrecommendations! Published in 2022 at "Proceedings of the National Academy of Sciences of the United States of America"
DOI: 10.1073/pnas.2202449119
Abstract: Significance The intrinsic sluggish kinetics of organodisulfides has hindered its further application in large-scale energy storage. In this work, we propose a unique redox mediator (carbon disulfide [CS2]) involving reversible C-S bond formation/breakage, which accelerates… read more here.
Keywords: mediator organodisulfides; carbon disulfide; redox mediator; disulfide redox ... See more keywords