Novel dirhenium(III,III) complexes with bridging diphenylphosphinomethane and dithiocarbamato ligands: A combined experimental and theoretical study
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DOI: 10.1016/j.poly.2021.115373
Abstract: Abstract Sodium salts of dimethyldithiocarbamate (LMe), diethyldithiocarbamate (LEt) and pyrrolidinedithiocarbamate (LPyr) react with the double-bonded diamagnetic dirhenium(III,III) complex Re2(μ-dppm)2(μ-Cl)2Cl4 (1) (dppm = Ph2PCH2PPh2) in refluxing ethanol to afford the diamagnetic substitution products of the type [Re2(µ-dppm)(η2-LR)2(µ-η2-LR)2](PF6)2, where… read more here.
Keywords: iii; iii iii; dirhenium iii; let ... See more keywords
The first examples of triply bonded dirhenium(II,II) complexes that contain bis(diphenylphosphino)methane and dithiocarbamato ligands: spectroscopic, structural, cytotoxicity and computational studies
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DOI: 10.1039/c9nj06122c
Abstract: Sodium salts of dimethyldithiocarbamate, diethyldithiocarbamate and pyrrolidinedithiocarbamate react with the triply bonded dirhenium (II,II) complex Re2(μ-Ph2PCH2PPh2)2Cl4 (1) in refluxing ethanol to afford the products of the type Re2(μ-Ph2PCH2PPh2)(LR)4 (2(LR)) where LR represents the dithiocarbamato ligands… read more here.
Keywords: bonded dirhenium; dirhenium complexes; dithiocarbamato ligands; triply bonded ... See more keywords