Macrocyclic Pd(II) dithiolate complexes as catalysts in Heck reactions
Sign Up to like & getrecommendations! Published in 2017 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2016.11.085
Abstract: Abstract The supramolecular palladium dithiolate complexes, [Pd2(dppe)2{S(C6H4)nS}]2(OTf)4 and [Pd2(dppe)2(SCH2C6H4CH2S)]4(OTf)8 (dppe = 1,2-bis(diphenylphosphino)ethane) has been investigated as highly stable and robust catalysts in Heck C-C coupling reactions. The arylation of butyl acrylate and styrene with various aryl bromides… read more here.
Keywords: heck reactions; complexes catalysts; catalysts heck; dithiolate complexes ... See more keywords
Diiron butane-1,2-dithiolate complexes with tris(2-thienyl)phosphine, tris(4-trifluoromethylphenyl)phosphine, or 4-(dimethylamino)phenyldiphenylphosphine: synthesis, characterization, X-ray crystal structures, and electrochemistry
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DOI: 10.1080/15421406.2020.1726669
Abstract: Abstract In this paper, three diiron butane-1,2-dithiolate complexes have been prepared and characterized. Treatment of the starting complex [Fe2(CO)6{µ-SCH2CH(CH2CH3)S}] (1) with a monophosphine ligand tris(2-thienyl)phosphine, tris(4-trifluoromethylphenyl)phosphine, or 4-(dimethylamino)phenyldiphenylphosphine and Me3NO·2H2O as the decarbonylating agent gave… read more here.
Keywords: diiron butane; phosphine; butane dithiolate; tris ... See more keywords