The oxygen-atom transfer reactions of Mo-diselenolene biomimetic complexes: A computational investigation
Sign Up to like & getrecommendations! Published in 2018 at "Computational and Theoretical Chemistry"
DOI: 10.1016/j.comptc.2018.07.003
Abstract: Abstract The aqueous Gibbs reaction and activation energies for the O-atom transfer mechanism of several Mo-bis(diselenolene) biomimetic complexes was investigated. The results obtained for the Mo-diselenolene biomimetic complexes were compared to analogous Mo-dithiolene biomimetic complexes… read more here.
Keywords: atom transfer; biomimetic complexes; diselenolene biomimetic; dithiolene ... See more keywords
Nickel bis(dithiolene) complexes for electrocatalytic hydrogen evolution: A computational study
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2018.03.007
Abstract: Abstract The substituent effect of dithiolene ligand on electrocatalytic activity of Ni bis(dithiolene) towards hydrogen evolution reaction (HER) are thoroughly explored with computational methods. A series of differently substituted dithiolene ligands are compared and evaluated.… read more here.
Keywords: nickel bis; hydrogen evolution; bis dithiolene; dithiolene ... See more keywords
Introducing Selenium in Single-Component Molecular Conductors Based on Nickel Bis(dithiolene) Complexes.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c00400
Abstract: Two selenated analogues of the all-sulfur single-component molecular conductor [Ni(Et-thiazdt)2] (Et-thiazdt = N-ethylthiazoline-2-thione-4,5-dithiolate) have been prepared from their precursor radical-anion complexes. Replacement of the thione by a selenone moiety gives the neutral [Ni(Et-thiazSedt)2] complex. It… read more here.
Keywords: selenium single; component molecular; single component; introducing selenium ... See more keywords
Ambipolar Nickel Dithiolene Complex Semiconductors: From One- to Two-Dimensional Electronic Structures Based upon Alkoxy Chain Lengths.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c08015
Abstract: Air-stable single-component ambipolar organic semiconductors that conduct both holes and electrons are highly desired but have been rarely realized. Neutral nickel bis(dithiolene) complexes are promising candidates that fulfill the stringent electronic requirements of shallow HOMO… read more here.
Keywords: nickel bis; dithiolene; air; effective intermolecular ... See more keywords
Broadband near-IR absorbing Au-dithiolene complexes bearing redox-active oligothiophene ligands.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt03915a
Abstract: A series of three homoleptic, monoanionic gold dithiolene complexes of oligothiophene ligands which coordinate via a central thiophene-3,4-dithiolate chelate are presented. The oligomer chains are three, five and seven thiophenes long and the complexes display… read more here.
Keywords: oligothiophene ligands; absorbing dithiolene; broadband near; near absorbing ... See more keywords
Redox chemistry of an anionic dithiolene radical.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c8dt04989k
Abstract: The redox chemistry of the first stable anionic dithiolene radical 1˙ was investigated by both reactivity and cyclic voltammetry studies. While one-electron reduction of 1˙ by Cp2Co or KC8 affords the corresponding dithiolate dimers 2… read more here.
Keywords: chemistry anionic; redox chemistry; chemistry; dithiolene ... See more keywords
Conducting chiral nickel(ii) bis(dithiolene) complexes: structural and electron transport modulation with the charge and the number of stereogenic centres
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Materials Chemistry C"
DOI: 10.1039/d1tc00439e
Abstract: Nickel(II) bis(dithiolene) complexes can provide crystalline conducting materials either in their monoanionic or neutral forms. Here we show that the use of chiral dithiolene ligands with one or two stereogenic centres, together with variation of… read more here.
Keywords: nickel bis; dddt; bis dithiolene; stereogenic centres ... See more keywords