A multi-method chemometric analysis in spectroelectrochemistry: Case study on molybdenum mono-dithiolene complexes.
Sign Up to like & getrecommendations! Published in 2021 at "Analytica chimica acta"
DOI: 10.1016/j.aca.2021.339065
Abstract: Spectroelectrochemical (SEC) analyses combine spectroscopic measurements with electrochemical techniques and can provide deep insight into complex multi-component chemical reaction systems. SEC experiments typically produce large amounts of spectroscopic data. Chemometric techniques are required for the… read more here.
Keywords: multi method; mono dithiolene; analysis; molybdenum mono ... See more keywords
Broadband near-IR absorbing Au-dithiolene complexes bearing redox-active oligothiophene ligands.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt03915a
Abstract: A series of three homoleptic, monoanionic gold dithiolene complexes of oligothiophene ligands which coordinate via a central thiophene-3,4-dithiolate chelate are presented. The oligomer chains are three, five and seven thiophenes long and the complexes display… read more here.
Keywords: oligothiophene ligands; absorbing dithiolene; broadband near; near absorbing ... See more keywords
Hydrogen bonding interactions in single component molecular conductors based on metal (Ni, Au) bis(dithiolene) complexes.
Sign Up to like & getrecommendations! Published in 2020 at "Dalton transactions"
DOI: 10.1039/d0dt00960a
Abstract: Introduction of hydrogen bonding (HB) interactions in single component conductors derived from nickel and gold bis(dithiolene) complexes is explored with the 2-alkylthio-1,3-thiazole-4,5-dithiolate (RS-tzdt) with R = CH2CH2OH through the preparation of the neutral [Ni(HOEtS-tzdt)2]0 (closed-shell)… read more here.
Keywords: bis dithiolene; hoets tzdt; hydrogen bonding; dithiolene complexes ... See more keywords
Conducting chiral nickel(ii) bis(dithiolene) complexes: structural and electron transport modulation with the charge and the number of stereogenic centres
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Materials Chemistry C"
DOI: 10.1039/d1tc00439e
Abstract: Nickel(II) bis(dithiolene) complexes can provide crystalline conducting materials either in their monoanionic or neutral forms. Here we show that the use of chiral dithiolene ligands with one or two stereogenic centres, together with variation of… read more here.
Keywords: nickel bis; dddt; bis dithiolene; stereogenic centres ... See more keywords
Iron and zinc porphyrin linked MoO(dithiolene) complexes in relevance to electron transfer between Mo-cofactor and cytochrome b5 in sulfite oxidase.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01863b
Abstract: Oxo-molybdenum (dithiolene) complexes covalently linked individually to iron and zinc porphyrin have been synthesized to show an electron transfer between the two metal centres in relevance to electron transfer from Mo-cofactor to cytochrome b5 domains… read more here.
Keywords: dithiolene complexes; iron zinc; zinc porphyrin; electron transfer ... See more keywords
Structure-activity relationship of anticancer and antiplasmodial gold bis(dithiolene) complexes.
Sign Up to like & getrecommendations! Published in 2024 at "Dalton transactions"
DOI: 10.1039/d4dt01458h
Abstract: Monoanionic gold bis(dithiolene) complexes were recently shown to display activity against ovarian cancer cells, Gram-positive bacteria, Candida strains and the rodent malaria parasite, P. berghei. To date, only monoanionic gold(III) bis(dithiolene) complexes with a thiazoline… read more here.
Keywords: bis dithiolene; gold; dithiolene complexes; anticancer antiplasmodial ... See more keywords
Electrostatic vs. electronic interactions within oxidized multinuclear Pt(bipyridine)(dithiolene) complexes.
Sign Up to like & getrecommendations! Published in 2024 at "Dalton transactions"
DOI: 10.1039/d4dt02514h
Abstract: Bi- and trimetallic platinum(bipyridine)(dithiolene) complexes involving different organic linkers between the redox active platinum(dithiolene) moieties have been synthesized and studied by electrochemistry and spectroelectrochemistry. Cyclic voltammetry experiments carried out on these multinuclear complexes in dichloromethane… read more here.
Keywords: dithiolene; dithiolene complexes; electrostatic electronic; oxidation ... See more keywords
HX-Linear and Nonlinear Optical Responsiveness of Rationally Designed Heteroleptic d8-Metallo-dithiolene Complexes
Sign Up to like & getrecommendations! Published in 2025 at "Molecules"
DOI: 10.3390/molecules30194004
Abstract: This work presents the HX-responsiveness of the following heteroleptic donor–M–acceptor dithiolene complexes: Bu4N[MII(L1)(L2)] [M = Ni(1), Pd(2), Pt(3)], where L1 is the chiral acceptor ligand [(R)-α-MBAdto = chiral (R)-(+)α-methylbenzyldithio-oxamidate] and L2 is the donor ligand… read more here.
Keywords: dithiolene complexes; nonlinear optical; linear nonlinear; optical responsiveness ... See more keywords