Halogen-Bonding-Mediated Radical Reactions: The Unexpected Behavior of Piperazine-Based Dithiooxamide Ligands in the Presence of Diiodine
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DOI: 10.1021/acs.inorgchem.2c02340
Abstract: N,N′-Dialkylpiperazine-2,3-dithiones (R2pipdt) were recognized as a class of hexa-atomic cyclic dithiooxamide ligands with peculiar charge-transfer donor properties toward soft electron-acceptors such as noble metal cations and diiodine. The latter interaction is nowadays better described as… read more here.
Keywords: halogen; mediated radical; halogen bonding; dithiooxamide ligands ... See more keywords