Synthesis of homometallic divalent lanthanide organoimides from benzyl complexes.
Sign Up to like & getrecommendations! Published in 2018 at "Chemical communications"
DOI: 10.1039/c8cc05234d
Abstract: The reaction of LnI2(thf)2 with benzyl potassium affords the homoleptic benzyl complexes [Ln(CH2Ph)2]n of samarium, europium, and ytterbium. In the cases of Eu and Yb, the treatment of [Ln(CH2Ph)2]n with one equivalent of 2,6-diisopropylaniline gives… read more here.
Keywords: lanthanide organoimides; benzyl; divalent lanthanide; synthesis homometallic ... See more keywords
Synthesis of homoleptic, divalent lanthanide (Sm, Eu) complexes via oxidative transmetallation.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt04230j
Abstract: The direct synthesis of neutral, divalent samarium and europium complexes supported by the bulky bis(tris-tert-butoxysilyl)amide (BTTSA) ligand via oxidative transmetallation is reported. Through the use of a copper(i) ligand complex, conventional lanthanide halide starting materials… read more here.
Keywords: via oxidative; divalent lanthanide; divalent; oxidative transmetallation ... See more keywords