Divalent Lanthanide Hydride Complexes
Sign Up to like & getrecommendations! Published in 2024 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.202400593
Abstract: Molecular hydride complexes have attracted recent attention, and divalent lanthanides as central atoms in particular are very interesting. They open up possibilities of combining hydride reactivity and lanthanide reactivity. To date, only Yb(II), Eu(II) and… read more here.
Keywords: lanthanide hydride; chemistry; hydride complexes; divalent lanthanide ... See more keywords
Synthesis of homometallic divalent lanthanide organoimides from benzyl complexes.
Sign Up to like & getrecommendations! Published in 2018 at "Chemical communications"
DOI: 10.1039/c8cc05234d
Abstract: The reaction of LnI2(thf)2 with benzyl potassium affords the homoleptic benzyl complexes [Ln(CH2Ph)2]n of samarium, europium, and ytterbium. In the cases of Eu and Yb, the treatment of [Ln(CH2Ph)2]n with one equivalent of 2,6-diisopropylaniline gives… read more here.
Keywords: lanthanide organoimides; benzyl; divalent lanthanide; synthesis homometallic ... See more keywords
Synthesis of homoleptic, divalent lanthanide (Sm, Eu) complexes via oxidative transmetallation.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt04230j
Abstract: The direct synthesis of neutral, divalent samarium and europium complexes supported by the bulky bis(tris-tert-butoxysilyl)amide (BTTSA) ligand via oxidative transmetallation is reported. Through the use of a copper(i) ligand complex, conventional lanthanide halide starting materials… read more here.
Keywords: via oxidative; divalent lanthanide; divalent; oxidative transmetallation ... See more keywords