Divergent pathways for reactions of CF3-containing Isobenzofuran-1-ones and amines
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Fluorine Chemistry"
DOI: 10.1016/j.jfluchem.2018.11.012
Abstract: Abstract Unprecedented isobenzofuran-1-ones (phthalides) with CF3 and ethoxy groups both at the 3-position were readily synthesized from the corresponding aromatic 1,2-diesters and reacted with a variety of primary amines to find out convenient conversion to… read more here.
Keywords: isobenzofuran ones; divergent pathways; pathways reactions; isobenzofuran ... See more keywords
Recent experiences and divergent pathways to transport decoupling
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Transport Geography"
DOI: 10.1016/j.jtrangeo.2020.102826
Abstract: Abstract This study examines the transport decoupling pathways of the 16 selected countries from 1990 to 2015. Transport carbon emissions (i.e. decarbonisation) and road traffic fatalities (i.e. defatalisation) have been chosen as proxies of environmental… read more here.
Keywords: transport; experiences divergent; divergent pathways; decoupling pathways ... See more keywords
Divergent pathways to isophthalates and naphthalate esters from methyl coumalate
Sign Up to like & getrecommendations! Published in 2018 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2018.09.058
Abstract: Abstract Methyl coumalate readily reacts with enamines at ambient temperature to give lactones, which can be further transformed into isophthalates and tetrahydronaphthoates. Both cyclic and acyclic enamines show good reactivity. Dehydrogenation of tetrahydronaphthoate 4a was… read more here.
Keywords: esters methyl; naphthalate esters; isophthalates naphthalate; pathways isophthalates ... See more keywords
(Z)-Trifluoromethyl-Trisubstituted Alkenes or Isoxazolines: Divergent Pathways from the Same Allene.
Sign Up to like & getrecommendations! Published in 2020 at "Organic letters"
DOI: 10.1021/acs.orglett.0c02546
Abstract: Because of a charge-dipole interaction involving nonbonding electron pairs on fluorine, protonation of trifluoromethyl allenes leads to tri- or tetrasubstituted alkenes with high (Z)-selectivity. Treatment of the same allenes with catalytic Au(I) initiates a reaction… read more here.
Keywords: pathways allene; alkenes isoxazolines; trisubstituted alkenes; isoxazolines divergent ... See more keywords