Cobalt-Catalyzed Ligand-Controlled Divergent Regioselective Reactions of 1,6-Enynes with Thiols
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DOI: 10.1021/acs.organomet.0c00179
Abstract: An efficient cobalt-catalyzed method for the synthesis of carbocyclic organosulfur compounds from 1,6-enynes and thiols has been developed. The significance of this methodology is the ability to gi... read more here.
Keywords: divergent regioselective; controlled divergent; enynes thiols; cobalt catalyzed ... See more keywords
Divergent Regioselective Csp2-H Difluoromethylation of Aromatic Amines Enabled by Nickel Catalysis.
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DOI: 10.1021/acs.orglett.2c01262
Abstract: Herein, the first catalytic protocol for nickel-catalyzed ortho or para position difluoromethylation of various aromatic amines has been developed with the assistance of a bidentate phosphine ligand, offering an invaluable synthesis means to construct extensive… read more here.
Keywords: divergent regioselective; difluoromethylation; aromatic amines; difluoromethylation aromatic ... See more keywords