Enantioselective Hydrothiolation: Diverging Cyclopropenes through Ligand Control.
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DOI: 10.1021/jacs.1c00939
Abstract: In this article, we advance Rh-catalyzed hydrothiolation through the divergent reactivity of cyclopropenes. Cyclopropenes undergo hydrothiolation to provide cyclopropyl sulfides or allylic sulfides. The choice of bisphosphine ligand dictates whether the pathway involves ring-retention or… read more here.
Keywords: hydrothiolation diverging; diverging cyclopropenes; cyclopropenes ligand; cyclopropyl ... See more keywords