Diverse reactivity of alkynes in C-H activation reactions.
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DOI: 10.1039/d2cc03294e
Abstract: Alkynes occupy a prominent role as a coupling partner in the transition metal-catalysed directed C-H activation reactions. Due to low steric requirements and linear geometry, alkynes can effectively coordinate with metal d-orbitals. This makes alkynes… read more here.
Keywords: reactivity alkynes; diverse reactivity; activation reactions; reactivity ... See more keywords
Diverse reactivity of a magnesium silanide toward ketones.
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DOI: 10.1039/d2cc03966d
Abstract: The reactivity of a molecular magnesium silanide toward ketones displays a significant variability of outcome, resulting in adduct formation, deprotonation, dearomatisation or deoxygenation, that is dependent on the structure and electronic character of the carbonyl-containing… read more here.
Keywords: magnesium silanide; silanide toward; diverse reactivity; toward ketones ... See more keywords