3-Thioaryne Intermediates for the Synthesis of Diverse Thioarenes.
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DOI: 10.1021/acs.orglett.9b01862
Abstract: The synthetic utility of 3-thioaryne intermediates has been demonstrated through an aryne relay approach. The efficient synthesis of o-silylaryl triflate-type 3-thioaryne precursors has been achieved by the regioselective silylthiolation of 3-(triflyloxy)arynes with silyl sulfides. Various… read more here.
Keywords: diverse thioarenes; intermediates synthesis; synthesis diverse; thioaryne intermediates ... See more keywords