Structural Diversity and Multielectron Reduction Reactivity of Samarium(II) Iodido-β-diketiminate Complexes Dependent on Tetrahydrofuran Content.
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DOI: 10.1021/acs.inorgchem.2c02101
Abstract: The molecular structures of complexes [Sm(Nacnac)I(thf)n] (Nacnac = HC(C(Me)Ndipp)2-, dipp = 2,6-diisopropylphenyl, thf = tetrahydrofuran) depending on the number of thf ligands are studied. The complete removal of thf from a known complex [Sm(Nacnac)I(thf)2] leads… read more here.
Keywords: thf; nacnac; sm3 nacnac; diversity multielectron ... See more keywords