Chiral phosphite-type ligands based on ((4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol) ((R,R)-TADDOL) with peripheral arylamino groups
Sign Up to like & getrecommendations! Published in 2017 at "Russian Chemical Bulletin"
DOI: 10.1007/s11172-017-1883-8
Abstract: New phosphite and amidophosphite inductors of chirality were obtained based on ((4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-diyl)bis(diphenylmethanol) ((R,R)-TADDOL) containing arylamino groups in the exocyclic substituents. Their use in the palladium-catalyzed enantioselective alkylation of (E)-1,3-diphenylallyl acetate with dimethyl malonate gave the… read more here.
Keywords: dioxolane diyl; diphenylmethanol taddol; diyl bis; bis diphenylmethanol ... See more keywords
Synthesis, crystal structure, DFT, docking and biological activity studies of (NZ,N’Z)-3,3’-(piperazine-1,4-diyl)bis(N-(-4-methyl benzylidene)propane-1-amine)
Sign Up to like & getrecommendations! Published in 2022 at "Materials Chemistry and Physics"
DOI: 10.1016/j.matchemphys.2021.125220
Abstract: Abstract The title compound (NZ,N’Z)-3,3’-(piperazine-1,4-diyl)bis(N-(-4-methyl benzylidene)propane-1-amine) (PMP) was synthesized by reacting N,N′-bis(3-aminopropyl)piperazine and 4- methyl benzaldehyde using microwave energy. The formed compound is characterized using FTIR, 1H and 13C NMR, UV–visible and elemental analysis techniques.… read more here.
Keywords: methyl; bis methyl; diyl bis; methyl benzylidene ... See more keywords
Synthesis, crystal structure, cytotoxic, antileishmanial activities and docking studies on N,N′-(ethane-1,2-diyl)bis(3-methylbenzamide)
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2017.12.010
Abstract: Abstract Amide derivatives have gained considerable attention because of their extensive range of biological activities and pharmaceutical applications. The current paper presents the synthesis of N, N′-(ethane-1,2-diyl) bis (3-methylbenzamide), (I), its molecular and crystal structure… read more here.
Keywords: crystal structure; bis methylbenzamide; diyl bis; structure ... See more keywords
The water-soluble indolium-based fluorescence probes for detection of the extreme acidity or extreme alkalinity
Sign Up to like & getrecommendations! Published in 2019 at "Tetrahedron"
DOI: 10.1016/j.tet.2019.130688
Abstract: Abstract In this work, 3,3′-(((1E,1′E)-(H,12H-5,11-methanodibenzo[b,f][1,5]diazocine-2,8-diyl)bis(ethene-2,1-diyl))bis(1,1-dimethyl-1H-benzo[e]indole-3-ium-2,3-diyl))bis(propane-1-sulfonate) (1), 3,3’-(((1E,1′E)-(6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine-2,8-diyl)bis(ethene-2,1-diyl))bis(3,3-dimethyl-3H-indole-1-ium-2,1-diyl))bis(propane-1-sulfonate) (2), 2,2’-((1E,1′E)-(6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine-2,8-diyl)bis(ethene-2,1-diyl))bis(1,3,3-trimethyl-3H-indol-1-ium) iodide (3) and 2,2’-((1E,1′E)-(6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine-2,8-diyl)bis(ethene-2,1-diyl))bis(1,1,3-trimethyl-1H-benzo[e]indol-3-ium) iodide (4) were designed and synthesized by ethylene bridging of the N-substituted indolium salts and the Troger’s Base (TB) framework. The probes… read more here.
Keywords: diyl; water; fluorescence probes; diyl bis ... See more keywords
Activation of the Aromatic Core of 3,3′-(Pyridine-2,6-diylbis(1H-1,2,3-triazole-4,1-diyl))bis(propan-1-ol)—Effects on Extraction Performance, Stability Constants, and Basicity
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.9b02325
Abstract: The “CHON” compatible water-soluble ligand 3,3′-(pyridine-2,6-diylbis(1H-1,2,3-triazole-4,1-diyl))bis(propan-1-ol) (PTD) has shown promise for selectively stripping actinide ions from an organic phase containing both actinide and lanthanide ions, by preferential complexation of the former. Aiming at improving its… read more here.
Keywords: pyridine; pyridine diylbis; diyl bis; triazole diyl ... See more keywords
Conversion of Methane into Methanol Using the [6,6′-(2,2′-Bipyridine-6,6′-Diyl)bis(1,3,5-Triazine-2,4-Diamine)](Nitrato-O)Copper(II) Complex in a Solid Electrolyte Reactor Fuel Cell Type
Sign Up to like & getrecommendations! Published in 2020 at "ACS Omega"
DOI: 10.1021/acsomega.0c01363
Abstract: The application of solid electrolyte reactors for methane oxidation to co-generation of power and chemicals could be interesting, mainly with the use of materials that could come from renewable sources and abundant metals, such as… read more here.
Keywords: solid electrolyte; copper complex; bis triazine; triazine diamine ... See more keywords
8,8′-(Benzo[c][1,2,5]thiadiazole-4,7-diyl)bis(quinolin-4(1H)-one): a twisted photosensitizer with AIE properties
Sign Up to like & getrecommendations! Published in 2021 at "RSC Advances"
DOI: 10.1039/d1ra06263h
Abstract: A new benzothiadiazole (BTZ) luminogen is prepared via the Suzuki–Miyaura Pd-catalysed C–C cross-coupling of 8-iodoquinolin-4(1H)-one and a BTZ bispinacol boronic ester. read more here.
Keywords: thiadiazole diyl; quinolin one; benzo thiadiazole; bis quinolin ... See more keywords
Bis{μ-2,2′-[(3,4-dithiahexane-1,6-diyl)bis(nitrilomethanylylidene)]bis(4-bromophenolato)-κ4 O,N,N′,O′}dicopper(II)
Sign Up to like & getrecommendations! Published in 2018 at "Acta Crystallographica Section E: Crystallographic Communications"
DOI: 10.1107/s2056989017017790
Abstract: The crystal structure of a novel binuclear copper(II) complex with a dianionic Schiff base derived from 5-bromosalicylic aldehyde and cysteamine prepared by direct synthesis is reported. read more here.
Keywords: bis nitrilomethanylylidene; diyl bis; bis; nitrilomethanylylidene bis ... See more keywords
Crystal structure of [μ-1κ2 C 1,C 4:2(1,2,3,4-η)-1,2,3,4-tetraphenylbuta-1,3-diene-1,4-diyl]bis(tricarbonylosmium)(Os—Os)
Sign Up to like & getrecommendations! Published in 2018 at "Acta Crystallographica Section E: Crystallographic Communications"
DOI: 10.1107/s2056989018011179
Abstract: A crystal structure of the osmole complex (μ-η4-C4Ph4)Os2(CO)6 revealed an eclipsed sawhorse molecular geometry with no bridging or semi-bridging carbonyl ligands. read more here.
Keywords: crystal structure; structure tetraphenylbuta; diyl bis; diene diyl ... See more keywords
(E)-6,6′-(Diazene-1,2-diyl)bis(1,10-phenanthrolin-5-ol) trichloromethane disolvate: a superconjugated ligand
Sign Up to like & getrecommendations! Published in 2019 at "Acta Crystallographica Section E: Crystallographic Communications"
DOI: 10.1107/s205698901900954x
Abstract: The preparation and structural characterization of the diazo-diphenanthroline compound, (E)-6,6′-(diazene-1,2-diyl)bis(1,10-phenanthrolin-5-ol) are described. The fully conjugated bis-phenanthroline molecule is expected to offer exciting new physical and chemical properties, and should form the basis of novel metal… read more here.
Keywords: diyl bis; bis phenanthrolin; diazene diyl; phenanthrolin trichloromethane ... See more keywords
Crystal structure of 1,1′-{(1E,1′E)-[4,4′-(9H-fluorene-9,9-diyl)bis(4,1-phenylene)]bis(azanylylidene)bis(methanylylidene)}bis(naphthalen-2-ol) dichlorobenzene monosolvate
Sign Up to like & getrecommendations! Published in 2020 at "Acta Crystallographica Section E: Crystallographic Communications"
DOI: 10.1107/s2056989020012104
Abstract: A novel bis(anil) compound was synthesized and structurally characterized. Theoretical calculations suggested that the new bis(hydroxyimine) will exhibit histone deacetylase SIRT2, histone deacetylase class III and histone deacetylase SIRT1 activities, and will act as inhibitor… read more here.
Keywords: crystal structure; diyl bis; fluorene diyl; histone deacetylase ... See more keywords