Crystal structures of two copper(I)–6,6′-dimethyl-2,2′-bipyridyl (dmbpy) compounds, [Cu(dmbpy)2]2[MF6]·xH2O (M = Zr, Hf; x = 1.134, 0.671)
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DOI: 10.1107/s2056989021007295
Abstract: The syntheses and crystal structures of two bimetallic molecular compounds, namely, bis(6,6′-dimethyl-2,2′-bipyridine)copper(I) hexafluoridozirconate(IV) 1.134-hydrate, [Cu(dmbpy)2]2[ZrF6]·1.134H2O (dmbpy = 6,6′-dimethyl-2,2′-bipyridyl, C12H12N2), (I), and bis(6,6′-dimethyl-2,2′-bipyridine)copper(I) hexafluoridohafnate(IV) 0.671-hydrate, [Cu(dmbpy)2]2[HfF6]·0.671H2O, (II), are reported. Apart from a slight site occupancy difference… read more here.
Keywords: copper; crystal structures; dimethyl bipyridyl; structures two ... See more keywords