LAUSR

Aromaticity-Driven Molecular Structural Variation and Electronic Configuration Alternation: An Example of Cyclic π Conjugation Involving a Mo-Mo δ Bond.

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0 Published in 2017 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.7b02133

Abstract: We have synthesized and characterized the mixed-ligand dimolybdenum paddlewheel complex Na[(DAniF)3Mo2(C3S5)] (Na[1]; DAniF = N,N'-di-p-anisylformamidinate, dmit = 1,3-dithiole-2-thione-4,5-dithiolate), which has a six-membered chelating [Mo2S2C2] ring created by equatorial coordination of the dmit (C3S5) ligand to… read more here.

Keywords: aromaticity; c3s5; bond; core ... See more keywords

Theoretical study of the photoconduction and photomagnetism of the BPY[Ni(dmit)2]2 molecular crystal.

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1 Published in 2019 at "Dalton transactions"

DOI: 10.1039/c9dt03102b

Abstract: The BPY[Ni(dmit)2]2 molecular crystal synthesized by Naito and coworkers (J. Am. Chem. Soc., 2012, 134, 18656) was characterized as a photo-magnetic-conductor. This crystal is a nonmagnetic semiconductor in the dark and becomes a magnetic conductor… read more here.

Keywords: bpy dmit; molecular crystal; photomagnetism; dmit ... See more keywords

A Discrepancy in Thermal Conductivity Measurement Data of Quantum Spin Liquid β′-EtMe3Sb[Pd(dmit)2]2 (dmit = 1,3-Dithiol-2-thione-4,5-dithiolate)

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3 Published in 2022 at "Crystals"

DOI: 10.3390/cryst12010102

Abstract: A molecular Mott insulator β′-EtMe3Sb[Pd(dmit)2]2 is a quantum spin liquid candidate. In 2010, it was reported that thermal conductivity of β′-EtMe3Sb[Pd(dmit)2]2 is characterized by its large value and gapless behavior (a finite temperature-linear term). In… read more here.

Keywords: dmit; spin liquid; thermal conductivity; quantum spin ... See more keywords

Thermoelectric Power of the Multi-Orbital Dimer Mott System, β-(CH3)4N[Pd(dmit)2]2

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1 Published in 2020 at "Journal of the Physical Society of Japan"

DOI: 10.7566/jpsj.89.034701

Abstract: (CH3)4N[Ni(dmit)2]2 shows ordinary T-linear thermoelectric power of −40 µV/K at room temperature coming from the quasi-one-dimensional band, but β-(CH3)4N[Pd(dmit)2]2 shows small negative thermoele... read more here.

Keywords: multi orbital; power multi; ch3 dmit; dmit ... See more keywords