Total Synthesis of DMOA-Derived Meroterpenoids: Achieving Selectivity in the Synthesis of (+)-Berkeleyacetal D and (+)-Peniciacetal I.
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DOI: 10.1021/jacs.4c15205
Abstract: The synthesis of complex natural products requires efficient control over chemoselectivity, stereoselectivity, and regioselectivity. Berkeleyacetals, a subfamily of 3,5-dimethylorsellinic acid (DMOA)-derived meroterpenoids, pose substantial synthetic challenges due to their densely functionalized and highly oxidized architectures,… read more here.
Keywords: total synthesis; derived meroterpenoids; dmoa derived; synthesis ... See more keywords