Noncovalent Synergy: Aurophilicity and Aryl Stacking in Bis(gold(I)aryl)-dmpm Complexes.
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DOI: 10.1021/acs.inorgchem.2c01442
Abstract: Bis(dimethylphosphino)methane (dmpm) was used as a ligand to synthesize four semi-supported dinuclear gold(I) complexes, dmpm(AuR)2 (R = Cl, C6H5, C6Cl5, and C6F5), which were studied concerning the synergistic effects of two weak noncovalent interactions: aurophilic… read more here.
Keywords: bis; dmpm; spectroscopy; aryl stacking ... See more keywords