On the consequences of the stereochemical activity of the Bi(iii) 6s2 lone pair in cyclen-based complexes. The [Bi(DO3A)] case.
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DOI: 10.1039/c8dt02602e
Abstract: We report a detailed study of the structure of the [Bi(DO3A)] complex both in the solid state and in solution. The X-ray crystal structure of [Bi(DO3A)] evidences the octa-coordination of the Bi(iii) ion, which is… read more here.
Keywords: 6s2 lone; coordination; lone pair; do3a complex ... See more keywords