Controlling enzyme hydrolysis of branched polymers synthesised using transfer-dominated branching radical telomerisation via telogen and taxogen selection
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DOI: 10.1038/s42004-024-01283-3
Abstract: With the ever-growing reliance on polymeric materials for numerous applications, new avenues to induce, design and control degradation are clearly important. Here, we describe a previously unreported approach to controlling enzymatic hydrolysis of high molecular… read more here.
Keywords: dominated branching; branched polymers; telogen; branching radical ... See more keywords
Using temperature to modify the reaction conditions and outcomes of polymers formed using transfer-dominated branching radical telomerisation (TBRT)
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DOI: 10.1039/d2ra06578a
Abstract: Transfer-dominated Branching Radical Telomerisation (TBRT) enables the production of branched polymers with step-growth backbones using radical telomerisation chemistry. By conducting identical TBRTs over a broad temperature range, the role of temperature in telomer formation and… read more here.
Keywords: temperature; radical telomerisation; dominated branching; transfer dominated ... See more keywords