Exploring Partners for the Domino α‐Arylation/Michael Addition Reaction Leading to Tetrahydroisoquinolines
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Organic Chemistry"
DOI: 10.1002/ejoc.201601300
Abstract: Sulfonates, sulfonamides and phosphonates are useful nucleophiles for palladium-catalyzed intramolecular alfa-arylation leading to tetrahydroisoquinolines. While the sulfonate alfa-arylation can be successfully combined in a domino process with a broad range of Michael acceptors, only vinyl… read more here.
Keywords: michael; partners domino; domino arylation; exploring partners ... See more keywords
Domino N-/C- or N-/N-/C-arylation of imidazoles to yield polyaryl imidazolium salts via atom-economical use of diaryliodonium salts.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc05237b
Abstract: Herein, we disclose a Cu-mediated domino di-/triarylation reaction of imidazoles to efficiently access polyaryl imidazolium salts in a single step by using two aryls as well as an anion of a diaryliodonium salt. The diarylation… read more here.
Keywords: polyaryl imidazolium; domino arylation; arylation imidazoles; imidazolium salts ... See more keywords