Super-Electron-Donor 2-Azaallyl Anions Enable Construction of Isoquinolines.
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DOI: 10.1021/acs.orglett.2c00140
Abstract: Herein is introduced the application of "super-electron-donor"(SED) 2-azaallyl anions in a tandem reduction/radical cyclization/radical coupling/aromatization protocol that enables the rapid construction of isoquinolines. The value of this transition-metal-free method is highlighted by the wide range… read more here.
Keywords: electron donor; super electron; donor azaallyl; construction isoquinolines ... See more keywords